Safety Guides

pH 4.00 Calibration Solution

Section 1: Product and Company Identification

Product name : pH 4.00 Calibration Solution
Synonyms/General Names: pH 4.00 Buffer solution
Product Use: For device calibration

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia

Section 2: Hazards Identification

Red liquid; no odor. CAUTION! Body tissue irritant. Target organs: None known This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) if used properly.

Section 3: Composition / Information on Ingredients

Potassium Hydrogen Phthalate: 10.21 g, 1-2%
Hydrochloric Acid: 1ml, \<1%
Water: (7732-18-5), 97-99%
Food coloring: \<1%

Section 4: First Aid Measures

Always seek professional medical attention after first aid measures are provided.

Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Poison Control immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.

Section 5: Fire Fighting Measures

Non-combustible solution. When heated to decomposition, emits acrid fumes.

Protective equipment and precautions for firefighters: Use foam or dry chemical to extinguish fire.

Firefighters should wear full fire fighting turn-out gear and respiratory protection (SCBA). Cool container with water spray. Material is not sensitive to mechanical impact or static discharge.

Section 6: Accidental Release Measures

Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Contain spill with sand or absorbent material and place in sealed bag or container for disposal. Ventilate and wash spill area after pickup is complete. See Section 13 for disposal information.

Section 7: Handling and Storage

Handling: Use with adequate ventilation and do not breathe dust or vapor. Avoid contact with skins, eyes, or clothing. Wash hands thoroughly after handling.
Storage: Store in General Storage Area with other items with no specific storage hazards. Store in a cool, dry, well-ventilated, locked store room away from incompatible materials.

Section 8: Exposure Controls / Personal Protection

Use ventilation to keep airborne concentrations below exposure limits. Have approved eyewash facility, safety shower, and fire extinguishers readily available. Wear chemical splash goggles and chemical resistant clothing such as gloves and aprons. Wash hands thoroughly after handling material and before eating or drinking.

Exposure guidelines: Sodium Hydroxide: OSHA PEL: 2 mg/m3, ACGIH: TLV: N/A, STEL: 2 mg/m3 ceiling.

Section 9: Physical and Chemical Properties

Section 10: Stability and Reactivity

Avoid heat and moisture.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Acids, alkalis,
Shelf life: Indefinite if stored properly.

Section 11: Toxicology Information

Acute Symptoms/Signs of exposure: Eyes: Redness, tearing, itching, burning, conjunctivitis.
Skin: Redness, itching.
Ingestion: Irritation and burning sensations of mouth and throat, nausea, vomiting and abdominal pain.
Inhalation: Irritation of mucous membranes, coughing, wheezing, shortness of breath,
Chronic Effects: No information found.
Sensitization: none expected
Sodium Hydroxide: LD50 [oral, rabbit]; N/A; LC50 [rat]; N/A; LD50 Dermal [rabbit]; N/A

Material has not been found to be a carcinogen nor produce genetic, reproductive, or developmental effects.

Section 12: Ecological Information

Ecotoxicity (aquatic and terrestrial): Not considered an
environmental hazard.

Section 13: Disposal Considerations

Check with all applicable local, regional, and national laws and regulations. Local regulations may be more stringent than regional or national regulations. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

Section 14: Transport Information

DOT Shipping Name: Not regulated by DOT
DOT Hazard Class:
Identification Number:
Canada TDG: Not regulated by TDG
Hazard Class:
UN Number:

Section 15: Regulatory Information

EINECS: Not listed
TSCA: All components are listed or are exempt
WHMIS Canada: Not WHMIS Controlled
California Proposition 65: Not listed

The product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

Section 16: Other Information

Current Issue Date: January 2011

Libelium believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Libelium has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. Libelium makes no warranty, expressed or implied, including (without limitation) warranties with respect to the completeness or continuing accuracy of the information contained herein or with respect to fitness for any particular use.

pH 7.00 Calibration Solution

Section 1: Product and Company Identification

Product name: pH 7.00 Calibration Solution
Synonyms/General Names: pH 7.00 Buffer solution
Product Use: For device calibration

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia

Section 2: Hazards Identification

Yellow liquid; no odor. CAUTION! Body tissue irritant. Target organs: None known This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) if used properly.

Section 3: Composition / Information on Ingredients

Potassium Dihydrogen Phosphate: 6.81g, \<1%
Sodium Hydroxide: 291mL, \<1%
Water: (7732-18-5), >99%
Food coloring: \<1%

Section 4: First Aid Measures

Always seek professional medical attention after first aid measures are provided.

Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Poison Control immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.

Section 5: Fire Fighting Measures

Noncombustible solution. When heated to decomposition, emits acrid fumes.

Protective equipment and precautions for firefighters: Use foam or dry chemical to extinguish fire.

Firefighters should wear full fire fighting turn-out gear and respiratory protection (SCBA). Cool container with water spray. Material is not sensitive to mechanical impact or static discharge.

Section 6: Accidental Release Measures

Section 7: Handling and Storage

Handling: Use with adequate ventilation and do not breathe dust or vapor. Avoid contact with skins, eyes, or clothing. Wash hands thoroughly after handling.
Storage: Store in General Storage Area with other items with no specific storage hazards. Store in a cool, dry, well-ventilated, locked store room away from incompatible materials.

Section 8: Exposure Controls / Personal Protection

Exposure guidelines: Sodium Hydroxide: OSHA PEL: 2 mg/m3, ACGIH: TLV: N/A, STEL: 2 mg/m3 ceiling.

Section 9: Physical and Chemical Properties

Section 10: Stability and Reactivity

Avoid heat and moisture.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Acids, alkalis,
Shelf life: Indefinite if stored properly.

Section 11: Toxicology Information

Acute Symptoms/Signs of exposure: Eyes: Redness, tearing, itching, burning, conjunctivitis. Skin: Redness, itching.
Ingestion: Irritation and burning sensations of mouth and throat, nausea, vomiting and abdominal pain.
Inhalation: Irritation of mucous membranes, coughing, wheezing, shortness of breath,
Chronic Effects: No information found.
Sensitization: none expected
Sodium Hydroxide: LD50 [oral, rabbit]; N/A; LC50 [rat]; N/A; LD50 Dermal [rabbit]; N/A

Material has not been found to be a carcinogen nor produce genetic, reproductive, or developmental effects.

Section 12: Ecological Information

Ecotoxicity (aquatic and terrestrial): Not considered an
environmental hazard.

Section 13: Disposal Considerations

Section 14: Transport Information

DOT Shipping Name: Not regulated by DOT
DOT Hazard Class:
Identification Number:
Canada TDG: Not regulated by TDG
Hazard Class:
UN Number:

Section 15: Regulatory Information

EINECS: Not listed
TSCA: All components are listed or are exempt
WHMIS Canada: Not WHMIS Controlled
California Proposition 65: Not listed

Section 16: Other Information

Current Issue Date: January 2011

pH 10.00 Calibration Solution

Section 1: Product and Company Identification

Product name: pH 10.00 Calibration Solution
Synonyms/General Names: pH 10.00 Buffer solution
Product Use: For device calibration

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia

Section 2: Hazards Identification

Blue liquid; no odor.

CAUTION! Body tissue irritant.

Target organs: None known

This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) if used properly.

Section 3: Composition / Information on Ingredients

Sodium Tetraborate: 4.77 g, 0.32-0.51%
Sodium Hydroxide: 183 mL, \<1%
Water: (7732-18-5), 99.1%

Section 4: First Aid Measures

Always seek professional medical attention after first aid measures are provided.

Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Poison Control immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.

Section 5: Fire Fighting Measures

Noncombustible solution. When heated to decomposition, emits acrid fumes.

Protective equipment and precautions for firefighters: Use foam or dry chemical to extinguish fire.

Firefighters should wear full fire fighting turn-out gear and respiratory protection (SCBA). Cool container with water spray. Material is not sensitive to mechanical impact or static discharge.

Section 6: Accidental Release Measures

Section 7: Handling and Storage

Handling: Use with adequate ventilation and do not breathe dust or vapor. Avoid contact with skins, eyes, or clothing. Wash hands thoroughly after handling.
Storage: Store in General Storage Area with other items with no specific storage hazards. Store in a cool, dry, well-ventilated, locked store room away from incompatible materials.

Section 8: Exposure Controls / Personal Protection

Exposure guidelines: Sodium hydroxide: OSHA PEL: Not Available, ACGIH: TLV: Not Available, STEL: Not Available.

Section 9: Physical and Chemical Properties

Section 10: Stability and Reactivity

Avoid heat and moisture.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Acids, alkalis,
Shelf life: Indefinite if stored properly.

Section 11: Toxicology Information

Acute Symptoms/Signs of exposure: Eyes: Redness, tearing, itching, burning, conjunctivitis.
Skin: Redness, itching.
Ingestion: Irritation and burning sensations of mouth and throat, nausea, vomiting and abdominal pain.
Inhalation: Irritation of mucous membranes, coughing, wheezing, shortness of breath,
Chronic Effects: No information found.
Sensitization: none expected
Sodium Hydroxide: LD50 [oral, rabbit]; N/A; LC50 [rat]; N/A; LD50 Dermal [rabbit]; N/A

Material has not been found to be a carcinogen nor produce genetic, reproductive, or developmental effects.

Section 12: Ecological Information

Ecotoxicity (aquatic and terrestrial): Not considered an environmental hazard.

Section 13: Disposal Considerations

Section 14: Transport Information

DOT Shipping Name: Not regulated by DOT

DOT Hazard Class:

Identification Number:

Canada TDG: Not regulated by TDG

Hazard Class:

UN Number:

Section 15: Regulatory Information

EINECS: Not listed
TSCA: All components are listed or are exempt
WHMIS Canada: Not WHMIS Controlled
California Proposition 65: Not listed

Section 16: Other Information

Current Issue Date: January 2011

Multi-ion Calibration Solution

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name: Multi-ion calibration solution Relevant identified uses: Ion-Selective Standard Solutions

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

2.1 Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. 2.2 Label elements Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

3. Composition/information on ingredients

Aqueous solution of ions

4. First aid measures

4.1 Description of frst aid measures If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labeling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available

5. Firefighting measures

Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture No data available 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 Further information no data

6. Accidental release measures

7. Handling and storage

7.1 Precautions for safe handling Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

8. Exposure controls/personal protection

8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove\'s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Respiratory protection is not required Control of environmental exposure No special environmental precautions required

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: Colourless b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point Melting point/range f) Initial boiling point and boiling range no data available g) Flash point not applicable h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure no data available l) Vapour density no data available m) Relative density 1,000 g/cm3 n) Water solubility no data available o) Partition coefficient: noctanol/water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available

10. Stability and reactivity

11. Toxicological information

12. Ecological information

12.1 Toxicity no data available 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential no data available 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.6 Other adverse effects no data available

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

14.1 UN number ADR/RID: - IMDG: - IATA: - 14.2 UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods 14.3 Transport hazard class(es) ADR/RID: - IMDG: - IATA: - 14.4 Packaging group ADR/RID: - IMDG: - IATA: - 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user no data available

15. Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture no data available 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out

16. Other information

Ion-Selective Standard Solutions The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product.

Calcium calibration solution

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Calcium Ions Relevant identified uses : Ion-Selective Standard Solutions

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

3. Composition/information on ingredients

Aqueous solution of Calcium Chloride (CaCl2) CAS Number: 10043-52-4

4. First aid measures

5. Firefighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: Colourless b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point Melting point/range: 384 °C f) Initial boiling point and boiling range no data available g) Flash point not applicable h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure no data available l) Vapour density no data available m) Relative density 1,009 g/cm3 n) Water solubility no data available o) Partition coefficient: noctanol/water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available

10. Stability and reactivity

11. Toxicological information

12. Ecological information

12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - > 13 mg/l - 96 h 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential no data available 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.6 Other adverse effects no data available

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

15. Regulatory information

16. Other information

Fluoride Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Fluoride Ions Relevant identified uses : Ion-Selective Standard Solutions

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

2.1 Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. 2.2 Label elements The product does not need to be labeled in accordance with EC directives or respective national laws. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

3. Composition/information on ingredients

Aqueous solution of Sodium Fluoride (NaF) CAS: 7681-49-4

4. First aid measures

4.1 Description of first aid measures If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labeling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available

5. Firefighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: Colourless b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point Melting point/range f) Initial boiling point and boiling range 100 °C at 1.000 hPa g) Flash point not applicable h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure no data available l) Vapour density no data available m) Relative density 1,000 g/cm3 n) Water solubility no data available o) Partition coefficient: noctanol/water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available

10. Stability and reactivity

11. Toxicological information

12. Ecological information

12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) → 13 mg/l - 96 h 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential no data available 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.6 Other adverse effects no data available

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

15. Regulatory information

16. Other information

Fluoroborate Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution tetrafluoroborate Ions Relevant identified uses : Ion-Selective Standard Solutions

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

3. Composition/information on ingredients

Aqueous solution of Sodium tetrafluoroborate (NaBF4) CAS Number: 13755-29-8

4. First aid measures

5. Firefighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: Colourless b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point Melting point/range: 384 °C f) Initial boiling point and boiling range no data available g) Flash point not applicable h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure no data available l) Vapour density no data available m) Relative density 2,47 g/mL at 25 °C n) Water solubility no data available o) Partition coefficient: noctanol/water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available

10. Stability and reactivity

11. Toxicological information

12. Ecological information

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product.

14. Transport information

15. Regulatory information

16. Other information

Lithium Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Lithium Ions REACH nº: A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. Relevant identified uses : Ion Standard Solutions for Ion Selective Electrodes

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

3. Composition/information on ingredients

Aqueous solution of Lithium Chloride (LiCl) CAS-No. 7447-41-8 EC-No. 231-212-3 Classification: Acute Tox. 4; Skin Irrit. 2; Eye; Irrit. 2; STOT SE 3; H302,H315, H319, H335 Xn, R22 - R36/37/38 Concentration \< 1% For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

4. First aid measures

4.1 Description of first aid measures If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available

5. Firefighting measures

6. Accidental release measures

7. Handling and storage

7.1 Precautions for safe handling No data available 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8 °C 7.3 Specific end use(s) no data available

8. Exposure controls/personal protection

8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove\'s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure No special environmental precautions required

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties a) Appearance Form: liquid b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point Melting point/range f) Initial boiling point and boiling range no data available g) Flash point not applicable h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure no data available l) Vapour density no data available m) Relative density no data available n) Water solubility no data available o) Partition coefficient: noctanol/water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available

10. Stability and reactivity

10.1 Reactivity no data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid no data available 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5 11. Toxicological information Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Ingestion May be harmful if swallowed. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: Not available

12. Ecological information

12.1 Toxicity No data available 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential no data available 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Harmful to aquatic life

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

15. Regulatory information

16. Other information

Ion-Selective Standard Solutions Text of H-code(s) and R-phrase(s) mentioned in Section 3 Acute Tox. Acute toxicity Eye Irrit. Eye irritation H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Skin Irrit. Skin irritation STOT SE Specific target organ toxicity - single exposure Xn Harmful R22 Harmful if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product.

Nitrate Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Nitrate Ions Relevant identified uses : Ion-Selective Standard Solutions

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

3. Composition/information on ingredients

Aqueous solution of Potassium Nitrate (KNO3) Natural product

4. First aid measures

5. Firefighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

9. Physical and chemical properties

10. Stability and reactivity

11. Toxicological information

12. Ecological information

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

15. Regulatory information

16. Other information

Nitrite Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Nitrite Ions REACH nº: A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. Relevant identified uses : Ion Standard Solutions for Ion Selective Electrodes

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

3. Composition/information on ingredients

Aqueous solution of Sodium Nitrite (NaNO2)

4. First aid measures

4.1 Description of first aid measures If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available

5. Firefighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

9. Physical and chemical properties

10. Stability and reactivity

11. Toxicological information

12. Ecological information

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

15. Regulatory information

16. Other information

Perchlorate Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Perchlorate Ions REACH nº: A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. Relevant identified uses : Ion Standard Solutions for Ion Selective Electrodes

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

3. Composition/information on ingredients

Aqueous solution of Perchlorate ions (ClO4-) 3.2 Mixtures No components need to be disclosed according to the applicable regulations.

4. First aid measures

4.1 Description of first aid measures If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available

5. Firefighting measures

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. Avoid breathing vapours, mist or gas. For personal protection see section 8. 6.2 Environmental precautions No special environmental precautions required. 6.3 Methods and materials for containment and cleaning up Sweep up and shovel. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13. 7. Handling and storage 7.1 Precautions for safe handling No data available 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 7.3 Specific end use(s) no data available

8. Exposure controls/personal protection

8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove\'s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure No special environmental precautions required

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties a) Appearance Form: liquid b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point Melting point/range f) Initial boiling point and boiling range no data available g) Flash point not applicable h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure no data available l) Vapour density no data available m) Relative density no data available n) Water solubility no data available o) Partition coefficient: noctanol/ water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available

10. Stability and reactivity

10.1 Reactivity no data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid no data available 10.5 Incompatible materials Strong bases, Strong acids, Amines, Phosphorus halides, Alcohols, Organic materials, Powdered metals, Strong reducing agents 10.6 Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5

11. Toxicological information

12. Ecological information

12.1 Toxicity No data available 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential no data available 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.6 Other adverse effects No data available

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

15. Regulatory information

16. Other information

Ion-Selective Standard Solutions The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knozledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product.

Bromide Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Bromide Ions Product Number : Br-SCxxxP Relevant identified uses : Ion-Selective Standard Solutions

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

3. Composition/information on ingredients

Aqueous solution of Potassium Bromide (KBr) CAS nº 7758-02-3 Hazardous ingredients according to Regulation (EC) No 1272/2008 Potassium Bromide Skin Irrit. 2; Eye Irrit. 2; STOT SE 3; H315, H319, H335 Concentration \<10% Hazardous ingredients according to Directive 1999/45/EC Potassium Bromide Xi, R36/37/38 Concentration \<10%

4. First aid measures

4.1 Description of first aid measures If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available

5. Firefighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166 (EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove\'s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Respiratory protection is not required Control of environmental exposure No special environmental precautions required

9. Physical and chemical properties

10. Stability and reactivity

11. Toxicological information

Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Ingestion May be harmful if swallowed. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation. Additional Information RTECS: Not available

12. Ecological information

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

15. Regulatory information

16. Other information

Chloride Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Chloride Ions Product Number : CL-SCxxxP Relevant identified uses : Ion-Selective Standard Solutions

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

3. Composition/information on ingredients

Aqueous solution of Potassium Chloride (KCl) CAS nº 7447-40-7

4. First aid measures

4.1 Description of first aid measures If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available

5. Firefighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

9. Physical and chemical properties

10. Stability and reactivity

11. Toxicological information

12. Ecological information

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

15. Regulatory information

16. Other information

Cupric Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Copper Ions Relevant identified uses : Ion-Selective Standard Solutions

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

2.1 Classification of the substance or mixture Acute aquatic toxicity (Category 1), H400 Chronic aquatic toxicity (Category 1), H410

2.2 Label elements Signal word Warning Hazard statement(s) H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P273 Avoid release to the environment P501 Dispose of contents/ container to an approved waste disposal plant. 2.3 Other hazards none

3. Composition/information on ingredients

Aqueous solution of Copper Sulfate (CuSO4) CAS Number: 7758-99-8

4. First aid measures

5. Firefighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: Blue b) Odour no data available c) Odour Threshold no data available d) pH : 3,7 - 4,5 e) Melting point/freezing point Melting point/range: 384 °C f) Initial boiling point and boiling range no data available g) Flash point not applicable h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure 9,7 hPa at 25 °C l) Vapour density no data available m) Relative density no data available n) Water solubility no data available o) Partition coefficient: noctanol/water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available

10. Stability and reactivity

10.1 Reactivity no data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid no data available 10.5 Incompatible materials Powdered metals, Anhydrous copper(II) sulfate, reacts violently with:, hydroxylamine, Magnesium 10.6 Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5

11. Toxicological information

Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure Inhalation - May cause respiratory irritation. Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Additional Information RTECS: Not available Symptoms of systemic copper poisoning may include: capillary damage, headache, cold sweat, weak pulse, and kidney and liver damage, central nervous system excitation followed by depression, jaundice, convulsions, paralysis, and coma. Death may occur from shock or renal failure. Chronic copper poisoning is typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humans with Wilson\'s disease. It has also been reported that copper poisoning has lead to hemolytic anemia and accelerates arteriosclerosis.

12. Ecological information

13. Disposal considerations

14. Transport information

14.1 UN number ADR/RID: 3082 IMDG: 3082 IATA: 3082 14.2 UN proper shipping name ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Copper sulphate) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Copper sulphate) IATA: Environmentally hazardous substance, liquid, n.o.s. (Copper sulphate) 14.3 Transport hazard class(es) ADR/RID: 9 IMDG: 9 IATA: * 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: yes 14.6 Special precautions for user no data available

15. Regulatory information

16. Other information

Iodide Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Iodide Ions Product Number : I-SCxxxP Relevant identified uses : Ion-Selective Standard Solutions

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

3. Composition/information on ingredients

Aqueous solution of Potassium Iodide (KI) CAS nº 7681-11-0 No components need to be disclosed according to the applicable regulations.

4. First aid measures

4.1 Description of first aid measures If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available

5. Firefighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls/personal protection

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: Colourlessb) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point Melting point/range f) Initial boiling point and boiling range no data available g) Flash point not applicable h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure no data available l) Vapour density no data available m) Relative density 1,000 g/cm3 n) Water solubility no data available o) Partition coefficient: noctanol/water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available

10. Stability and reactivity

10.1 Reactivity no data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid no data available 10.5 Incompatible materials Strong reducing agents, Nickel, Strong acids, and its alloys, Steel (all types and surface treatments), Aluminum, Alkali metals, Brass, Magnesium, Zinc, cadmium, Copper 10.6 Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5

11. Toxicological information

12. Ecological information

13. Disposal considerations

Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

15. Regulatory information

16. Other information

Silver Calibration Kit

Safety Data Sheet According to Regulation (EC) No. 1907/2006 Version 1.0 Revision Date: 27.02.2013

1. Identification Of The Substance/Mixture

Product Name : Standard Solution Silver Nitrate Relevant identified uses : Ion-Selective Standard Solutions

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia INTCF - Instituto Nacional de toxicología y Ciencias Forenses - 91 562 04 20

2. Hazards identification

2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Skin corrosion (Category 2), H315 Eye irritation ( Category 2ª), -H319 Chronic aquatic toxicity (Category 1), H410 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC C Corrosive R34 N Dangerous for the environment R50/53 O Oxidising R 8, R22 For the full text of the R-phrases mentioned in this Section, see Section 16. 2.2Label elements Labeling according Regulation (EC) No 1272/2008

Pictogram Signal word Danger Hazard statement(s). H314/319 Causes severe skin burns and eye damage. H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P273 Avoid release to the environment. P302+352 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplemental Hazard Statements

3. Composition/information on ingredients

Aqueous solution of AgNO3 Formula : AgNO3 CAS-No. : 7761-88-8

4. First aid measures

4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labeling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed no data available

5. Firefighting measures

Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Nitrogen oxides (NOx), Silver/silver oxides Container explosion may occur under fire conditions. 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 Further information Use water spray to cool unopened containers.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13.

7. Handling and storage

7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition - No smoking. Keep away from heat and sources of ignition. For precautions see section 2.2 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 7.3 Specific end use(s) Apart from the uses mentioned in section 1 no other specific uses are stipulated

8. Exposure controls/personal protection

8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove\'s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point Melting point/range: 212 °C - dec. f) Initial boiling point and boiling range 440 °C - Decomposes on heating. g) Flash point not applicable h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure no data available l) Vapour density no data available m) Relative density 4.350 g/cm3 at 25 °C n) Water solubility no data available o) Partition coefficient: noctanol/water log Pow: 5 p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties The substance or mixture is classified as oxidizing with the category 2

10. Stability and reactivity

10.1 Reactivity no data available 10.2 Chemical stability Decomposes on exposure to light. Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid Light 10.5 Incompatible materials Strong reducing agents, Alcohols, Ammonia, Magnesium, Strong bases 10.6 Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5

11. Toxicological information

Information on toxicological effects Acute toxicity LD50 Oral - Rat - 1.173 mg/kg Remarks: Behavioral:Tetany. Cyanosis Diarrhoea Skin corrosion/irritation No data available Serious eye damage/eye irritation Eyes - Rabbit Result: Severe eye irritation Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS: VW4725000

12. Ecological information

12.1 Toxicity Toxicity to fish mortality NOEC - Oncorhynchus mykiss (rainbow trout) - 0,108 mg/l - 96,0 h mortality LOEC - Oncorhynchus mykiss (rainbow trout) - > 0,007 mg/l - 7,0 d LC50 - Leuciscus idus (Golden orfe) - 0,029 mg/l - 96,0 h LC50 - Oncorhynchus mykiss (rainbow trout) - 0,006 mg/l - 96,0 h Toxicity to daphnia and other aquatic invertebrates 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential Bioaccumulation Lepomis macrochirus - 60 d - 70 μg/l Bioconcentration factor (BCF): 120 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Harmful to aquatic life.

13. Disposal considerations

Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.

14. Transport information

14.1 UN number ADR/RID: 1493 IMDG: 1493 IATA: 1493 14.2 UN proper shipping name ADR/RID: SILVER NITRATE IMDG: SILVER NITRATE IATA: Silver nitrate 14.3 Transport hazard class(es) ADR/RID: 5.1 IMDG: 5.1 IATA: 5.1 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: no 14.6 Special precautions for user no data available

15. Regulatory information

16. Other information

Full text of H-Statements referred to under sections 2 and 3. Acute Tox. Acute toxicity Aquatic Acute Acute aquatic toxicity Aquatic Chronic Chronic aquatic toxicity H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Ox. Sol. Oxidizing solids Skin Corr. Skin corrosion Full text of R-phrases referred to under sections 2 and 3 C Corrosive N Dangerous for the environment O Oxidising R 8 Contact with combustible material may cause fire. R22 Harmful if swallowed. R34 Causes burns. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Designed use Ion-Selective Standard Solutions The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product.

Reference Sensor Probe [PRO] Maintenance Solution

Section 1: Product and company identification

Product name: Lithium Acetate Solution

Product use: Solution to storage and/or conditioning Reference Electrodes (PRO version)

NFPA ratings: Health: 0 Flammability: 0 Reactivity: 0

#US/Canada/International:

24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887

#Spain:

Centro Nacional de Toxicología Teléfono: 91 5620420 http://www.mju.es/toxicologia

Section 2: Composition/ information on ingredients

Aqueous solution of Lithium Acetate 3M (3 mol)

CAS-No. 546-89-4

EC-No. 208-914-3

No components need to be disclosed according to the applicable regulations.

Section 3: Hazards identification

Classification of the substance or mixture:

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC.

Label elements:

Not a hazardous substance or mixture according to EC-directives
67/548/EEC or 1999/45/EC.

Other hazards:

This substance/mixture contains no components considered to be
either persistent, bioaccumulative and toxic (PBT), or very
persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher.

Section 4: First aid measures

Description of first aid measures:

If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact: Wash off with soap and plenty of water.
In case of eye contact: Flush eyes with water as a precaution.
If swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water.

Most important symptoms and effects, both acute and delayed:

The most important known symptoms and effects are described in the
labelling (see section 2.2) and/or in section 11.

Indication of any immediate medical attention and special treatment needed:

No data available.

Section 5: Fire fighting measures

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture: No data available.
Advice for firefighters: Wear self contained breathing apparatus for fire fighting if necessary.
Further information: no data.

Section 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures: Avoid dust formation. Avoid breathing vapours, mist or gas. For personal protection see section 8.

Environmental precautions: No special environmental precautions required.

Methods and materials for containment and cleaning up: Sweep up and shovel. Keep in suitable, closed containers for disposal.

Reference to other sections: For disposal see section 13.

Section 7: Handling and storage

Precautions for safe handling: Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.

Conditions for safe storage, including any incompatibilities: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non Combustible Solids.

Specific end use(s): Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

Section 8: Exposure controls/ personal protection

Control parameters:

Components with workplace control parameters

Exposure controls:

Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment:
- Eye/face protection: Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
- Skin protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove\'s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
- Body Protection: The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
- Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure: No special environmental precautions required

Section 9: Physical and chemical properties

Appearance Form: liquid

Odour: no data available

Odour Threshold: no data available

pH: no data available

Melting point/freezing point

Initial boiling point and boiling range: no data available

Flash point: not applicable

Evapouration rate no: data available

Flammability (solid, gas): no data available

Upper/lower flammability or explosive limits: no data available

Vapour pressure: no data available

Vapour density: no data available

Relative density: no data available

Water solubility: no data available

Partition coefficient: noctanol/water: no data available

Auto-ignition temperature: no data available

Decomposition temperature: no data available

Viscosity: no data available

Explosive properties: no data available

Oxidizing properties: no data available

Section 10: Stability and reactivity

Reactivity: no data available

Chemical stability: Stable under recommended storage conditions.

Possibility of hazardous reactions: no data available

Conditions to avoid: no data available

Incompatible materials: Strong oxidizing agents

Hazardous decomposition products: Other decomposition products - no data available. In the event of fire: see section 5

Section 11: Toxicological information

Information on toxicological effects:

Acute toxicity: no data available
Skin corrosion/irritation: no data available
Serious eye damage/eye irritation: no data available
Respiratory or skin sensitisation: no data available
Germ cell mutagenicity: Mouse Cytogenetic analysis. Mouse Sister chromatid exchange
Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: Possible risk of congenital malformation in the fetus
Specific target organ toxicity - single exposure: No data available
Specific target organ toxicity - repeated exposure: no data available
Aspiration hazard: no data available

Potential health effects:

Inhalation: May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion: May be harmful if swallowed.
Skin: May be harmful if absorbed through skin. May cause skin irritation.
Eyes: May cause eye irritation.
Signs and Symptoms of Exposure: To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Additional Information:

RTECS: AI5450000 - Large doses of lithium ion have caused dizziness
and prostration, and can Dehydration, weight loss, dermatological
effects, and thyroid disturbance include slurred speech, blurred
vision, sensory loss, ataxia, and convuls effects such as tremor,
clonus, and hyperactive reflexes may occur as a r, To the best of
our knowledge, the chemical, physical, and toxicological properties
have not been thoroughly investigated.

Section 12: Ecological information

Toxicity: No data available

Persistence and degradability: no data available

Bioaccumulative potential: no data available

Mobility in soil: no data available

Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects: Harmful to aquatic life

Section 13: Disposal considerations

Waste treatment methods:

Product: Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging: Dispose of as unused product.

Section 14: Transport information

UN number:

ADR/RID: - IMDG: - IATA: -

UN proper shipping name:

ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods

Transport hazard class(es):

ADR/RID: - IMDG: - IATA: -

Packaging group:

ADR/RID: - IMDG: - IATA: -

Environmental hazards:

ADR/RID: no IMDG Marine pollutant: no IATA: no

Special precautions for user: no data available

Section 15: Regulatory information

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Safety, health and environmental regulations/legislation specific for the substance or mixture: no data available
Chemical Safety Assessment: no data available

Section 16: Other information

Ion-Selective ElectrodeSolutions

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox. Acute toxicity

Eye Irrit. Eye irritation

H302 Harmful if swallowed.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

Skin Irrit. Skin irritation

STOT SE Specific target organ toxicity - single exposure

Xn Harmful

R22 Harmful if swallowed.

R36/37/38 Irritating to eyes, respiratory system and skin.

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product.

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