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Section 1: Product and Company Identification
Product name : pH 4.00 Calibration Solution
Synonyms/General Names: pH 4.00 Buffer solution
Product Use: For device calibration
#US/Canada/International:
24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887
#Spain:
Centro Nacional de Toxicología Teléfono: 91 5620420
Section 2: Hazards Identification
Red liquid; no odor. CAUTION! Body tissue irritant. Target organs: None known This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) if used properly.
Section 3: Composition / Information on Ingredients
Potassium Hydrogen Phthalate: 10.21g, 1-2%
Hydrochloric Acid: 1ml, \<1%
Water: (7732-18-5), 97-99%
Food coloring: \<1%
Section 4: First Aid Measures
Always seek professional medical attention after first aid measures are provided.
Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Poison Control immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink.Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.
Section 5: Fire Fighting Measures
Non-combustible solution. When heated to decomposition, emits acrid fumes.
Protective equipment and precautions for firefighters: Use foam or dry chemical to extinguish fire.
Firefighters should wear full fire fighting turn-out gear and respiratory protection (SCBA). Cool container with water spray. Material is not sensitive to mechanical impact or static discharge.
Section 6: Accidental Release Measures
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Contain spill with sand or absorbent material and place in sealed bag or container for disposal. Ventilate and wash spill area after pickup is complete. See Section 13 for disposal information.
Section 7: Handling and Storage
Handling: Use with adequate ventilation and do not breathe dust or vapor. Avoid contact with skins, eyes, or clothing.Wash hands thoroughly after handling.
Storage: Store in General Storage Area with other items with no specific storage hazards. Store in a cool, dry, well-ventilated, locked store room away from incompatible materials.
Section 8: Exposure Controls / Personal Protection
Use ventilation to keep airborne concentrations below exposure limits. Have approved eyewash facility, safety shower, and fire extinguishers readily available. Wear chemical splash goggles and chemical resistant clothing such as gloves and aprons. Wash hands thoroughly after handling material and before eating or drinking.
Exposure guidelines: Sodium Hydroxide: OSHA PEL: 2 mg/m3, ACGIH: TLV: N/A, STEL: 2 mg/m3 ceiling.
Section 9: Physical and Chemical Properties
Molecular formula:
N/A
Appearance:
Red liquid
Molecular weight:
N/A
Odor:
No odor
Specific Gravity:
1.00 g/mL @ 20°C
Odor Threshold:
N/A
Vapor Density (air=1):
0.7 (water)
Solubility:
Complete
Melting Point Freezes:
@ ~0 °C
Evaporation rate:
N/A (Butyl acetate = 1)
Boiling Point/Range:
~100°C
Partition Coefficient:
N/A (log POW)
Vapor Pressure (20°C):
N/A
pH:
4.0
Flash Point:
N/A
LEL:
N/A
Autoignition Temp:
N/A
UEL:
N/A
Section 10: Stability and Reactivity
Avoid heat and moisture.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Acids, alkalis,
Shelf life: Indefinite if stored properly.
Section 11: Toxicology Information
Acute Symptoms/Signs of exposure: Eyes: Redness, tearing, itching, burning, conjunctivitis.
Skin: Redness, itching.
Ingestion: Irritation and burning sensations of mouth and throat, nausea, vomiting and abdominal pain.
Inhalation: Irritation of mucous membranes, coughing, wheezing, shortness of breath,
Chronic Effects: No information found.
Sensitization: none expected
Sodium Hydroxide: LD50 [oral, rabbit]; N/A; LC50 [rat]; N/A; LD50 Dermal [rabbit]; N/A
Material has not been found to be a carcinogen nor produce genetic, reproductive, or developmental effects.
Section 12: Ecological Information
Ecotoxicity (aquatic and terrestrial): Not considered an environmental hazard.
Section 13: Disposal Considerations
Check with all applicable local, regional, and national laws and regulations. Local regulations may be more stringent than regional or national regulations. Small amounts of this material may be suitable for sanitary sewer or trash disposal.
Section 14: Transport Information
DOT Shipping Name: Not regulated by DOT
DOT Hazard Class:
Identification Number:
Canada TDG: Not regulated by TDG
Hazard Class:
UN Number:
Section 15: Regulatory Information
EINECS: Not listed
TSCA: All components are listed or are exempt
WHMIS Canada: Not WHMIS Controlled
California Proposition 65: Not listed
The product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
Section 16: Other Information
Current Issue Date: January 2011
Disclaimer: Libelium believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Libelium has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. Libelium makes no warranty, expressed or implied, including (without limitation) warranties with respect to the completeness or continuing accuracy of the information contained herein or with respect to fitness for any particular use.
Section 1: Product and Company Identification
Product name: pH 7.00 Calibration Solution
Synonyms/General Names: pH 7.00 Buffer solution
Product Use: For device calibration
#US/Canada/International:
24 Hour Emergency Information Telephone Numbers
CHEMTREC (USA): 800.424.9300
CANUTEC (Canada): 613.424.6666
International 703-527-3887
#Spain:
Centro Nacional de Toxicología
Teléfono: 91 5620420
Section 2: Hazards Identification
Yellow liquid; no odor. CAUTION! Body tissue irritant. Target organs: None known This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) if used properly.
Section 3: Composition / Information on Ingredients
Potassium Dihydrogen Phosphate: 6.81g, \<1%
Sodium Hydroxide: 291mL, \<1%
Water: (7732-18-5), >99%
Food coloring: \<1%
Section 4: First Aid Measures
Always seek professional medical attention after first aid measures are provided.
Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Poison Control immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.
Section 5: Fire Fighting Measures
Noncombustible solution. When heated to decomposition, emits acrid fumes.
Protective equipment and precautions for firefighters: Use foam or dry chemical to extinguish fire.
Firefighters should wear full fire fighting turn-out gear and respiratory protection (SCBA). Cool container with water spray. Material is not sensitive to mechanical impact or static discharge.
Section 6: Accidental Release Measures
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Contain spill with sand or absorbent material and place in sealed bag or container for disposal. Ventilate and wash spill area after pickup is complete. See Section 13 for disposal information.
Section 7: Handling and Storage
Handling: Use with adequate ventilation and do not breathe dust or vapor. Avoid contact with skins, eyes, or clothing. Wash hands thoroughly after handling.
Storage: Store in General Storage Area with other items with no specific storage hazards. Store in a cool, dry, well-ventilated, locked store room away from incompatible materials.
Section 8: Exposure Controls / Personal Protection
Use ventilation to keep airborne concentrations below exposure limits. Have approved eyewash facility, safety shower, and fire extinguishers readily available. Wear chemical splash goggles and chemical resistant clothing such as gloves and aprons. Wash hands thoroughly after handling material and before eating or drinking.
Exposure guidelines: Sodium Hydroxide: OSHA PEL: 2 mg/m3, ACGIH: TLV: N/A, STEL: 2 mg/m3 ceiling.
Section 9: Physical and Chemical Properties
Molecular formula:
N/A
Appearance:
Yellow liquid
Molecular weight:
N/A
Odor:
No odor
Specific Gravity:
1.00 g/mL @ 20°C
Odor Threshold:
N/A
Vapor Density (air=1):
0.7 (water)
Solubility:
Complete
Melting Point Freezes:
@ ~0 °C
Evaporation rate:
N/A (Butyl acetate = 1)
Boiling Point/Range:
~100°C
Partition Coefficient:
N/A (log POW)
Vapor Pressure (20°C):
N/A
pH:
7.0
Flash Point:
N/A
LEL:
N/A
Autoignition Temp:
N/A
UEL:
N/A
Section 10: Stability and Reactivity
Avoid heat and moisture.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Acids, alkalis,
Shelf life: Indefinite if stored properly.
Section 11: Toxicology Information
Acute Symptoms/Signs of exposure: Eyes: Redness, tearing, itching, burning, conjunctivitis. Skin: Redness, itching.
Ingestion: Irritation and burning sensations of mouth and throat, nausea, vomiting and abdominal pain.
Inhalation: Irritation of mucous membranes, coughing, wheezing, shortness of breath,
Chronic Effects: No information found.
Sensitization: none expected
Sodium Hydroxide: LD50 [oral, rabbit]; N/A; LC50 [rat]; N/A; LD50 Dermal [rabbit]; N/A
Material has not been found to be a carcinogen nor produce genetic, reproductive, or developmental effects.
Section 12: Ecological Information
Ecotoxicity (aquatic and terrestrial): Not considered an environmental hazard.
Section 13: Disposal Considerations
Check with all applicable local, regional, and national laws and regulations. Local regulations may be more stringent than regional or national regulations. Small amounts of this material may be suitable for sanitary sewer or trash disposal.
Section 14: Transport Information
DOT Shipping Name: Not regulated by DOT
DOT Hazard Class:
Identification Number:
Canada TDG: Not regulated by TDG
Hazard Class:
UN Number:
Section 15: Regulatory Information
EINECS: Not listed
TSCA: All components are listed or are exempt
WHMIS Canada: Not WHMIS Controlled
California Proposition 65: Not listed
The product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
Section 16: Other Information
Current Issue Date: January 2011
Disclaimer: Libelium believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Libelium has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. Libelium makes no warranty, expressed or implied, including (without limitation) warranties with respect to the completeness or continuing accuracy of the information contained herein or with respect to fitness for any particular use.
Section 1: Product and Company Identification
Product name: pH 10.00 Calibration Solution
Synonyms/General Names: pH 10.00 Buffer solution
Product Use: For device calibration
#US/Canada/International:
24 Hour Emergency Information Telephone Numbers
CHEMTREC (USA): 800.424.9300
CANUTEC (Canada): 613.424.6666
International 703-527-3887
#Spain:
Centro Nacional de Toxicología
Teléfono: 91 5620420
Section 2: Hazards Identification
Blue liquid; no odor. CAUTION! Body tissue irritant. Target organs: None known This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) if used properly.
Section 3: Composition / Information on Ingredients
Sodium Tetraborate: 4.77g, 0.32-0.51%
Sodium Hydroxide: 183mL, \<1%
Water: (7732-18-5), 99.1%
Section 4: First Aid Measures
Always seek professional medical attention after first aid measures are provided.
Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Poison Control immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.
Section 5: Fire Fighting Measures
Noncombustible solution. When heated to decomposition, emits acrid fumes.
Protective equipment and precautions for firefighters: Use foam or dry chemical to extinguish fire.
Firefighters should wear full fire fighting turn-out gear and respiratory protection (SCBA). Cool container with water spray. Material is not sensitive to mechanical impact or static discharge.
Section 6: Accidental Release Measures
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Contain spill with sand or absorbent material and place in sealed bag or container for disposal. Ventilate and wash spill area after pickup is complete. See Section 13 for disposal information.
Section 7: Handling and Storage
Handling: Use with adequate ventilation and do not breathe dust or vapor. Avoid contact with skins, eyes, or clothing.Wash hands thoroughly after handling.
Storage: Store in General Storage Area with other items with no specific storage hazards. Store in a cool, dry, well-ventilated, locked store room away from incompatible materials.
Section 8: Exposure Controls / Personal Protection
Use ventilation to keep airborne concentrations below exposure limits. Have approved eyewash facility, safety shower, and fire extinguishers readily available. Wear chemical splash goggles and chemical resistant clothing such as gloves and aprons. Wash hands thoroughly after handling material and before eating or drinking. Use NIOSH-approved respirator with an dust cartridge.
Exposure guidelines: Sodium hydroxide: OSHA PEL: Not Available, ACGIH: TLV: Not Available, STEL: Not Available.
Section 9: Physical and Chemical Properties
Molecular formula:
N/A
Appearance:
Blue liquid
Molecular weight:
N/A
Odor:
No odor
Specific Gravity:
1.00 g/mL @ 20°C
Odor Threshold:
N/A
Vapor Density (air=1):
0.7 (water)
Solubility:
Complete
Melting Point Freezes:
@ ~0 °C
Evaporation rate:
N/A (Butyl acetate = 1)
Boiling Point/Range:
~100°C
Partition Coefficient:
N/A (log POW)
Vapor Pressure (20°C):
N/A
pH:
10.0
Flash Point:
N/A
LEL:
N/A
Autoignition Temp:
N/A
UEL:
N/A
Section 10: Stability and Reactivity
Avoid heat and moisture.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Acids, alkalis,
Shelf life: Indefinite if stored properly.
Section 11: Toxicology Information
Acute Symptoms/Signs of exposure: Eyes: Redness, tearing, itching, burning, conjunctivitis.
Skin: Redness, itching.
Ingestion: Irritation and burning sensations of mouth and throat, nausea, vomiting and abdominal pain.
Inhalation: Irritation of mucous membranes, coughing, wheezing, shortness of breath,
Chronic Effects: No information found.
Sensitization: none expected
Sodium Hydroxide: LD50 [oral, rabbit]; N/A; LC50 [rat]; N/A; LD50 Dermal [rabbit]; N/A
Material has not been found to be a carcinogen nor produce genetic, reproductive, or developmental effects.
Section 12: Ecological Information
Ecotoxicity (aquatic and terrestrial): Not considered an environmental hazard.
Section 13: Disposal Considerations
Check with all applicable local, regional, and national laws and regulations. Local regulations may be more stringent than regional or national regulations. Small amounts of this material may be suitable for sanitary sewer or trash disposal.
Section 14: Transport Information
DOT Shipping Name: Not regulated by DOT
DOT Hazard Class:
Identification Number:
Canada TDG: Not regulated by TDG
Hazard Class:
UN Number:
Section 15: Regulatory Information
EINECS: Not listed
TSCA: All components are listed or are exempt
WHMIS Canada: Not WHMIS Controlled
California Proposition 65: Not listed
The product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
Section 16: Other Information
Current Issue Date: January 2011
Disclaimer: Libelium believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Libelium has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. Libelium makes no warranty, expressed or implied, including (without limitation) warranties with respect to the completeness or continuing accuracy of the information contained herein or with respect to fitness for any particular use.
Section 1: Product and company identification
Product name: 0 Dissolved Oxygen Solution
Product use: Reagent
NFPA ratings: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0
#US/Canada/International:
24 Hour Emergency Information Telephone Numbers
CHEMTREC (USA): 800.424.9300
CANUTEC (Canada): 613.424.6666
International 703-527-3887
#Spain:
Centro Nacional de Toxicología
Teléfono: 91 5620420
Section 2: Composition/information on ingredients
COMPONENT
CAS NO.
%
LD50 mg/kg
Sodium Sulfite (Na2SO3)
7757-83-7
5
820 (ORL-MUS)
Cobalt Chloride Hexahydrate (CoCl2.6H2O)
7791-13-1
<0.001
766 (ORL-RAT)
Deionized Water (H2O)
7732-18-5
>94
190,000 (IPR-MUS)
Section 3: Hazards identification
May cause irritation to eyes and skin. May be harmful if swallowed. May cause allergic respiratory and skin reaction.
Target organs: Eyes, skin, respiratory tract.
Acute toxicity: May cause gastric irritation by the liberation of sulfurous acid. Ingestion of large amount of sodium sulfite may cause circulatory disturbances, diarrhea, and central nervous system depression.
Chronic toxicity: Cobalt compounds may cause cancer and adverse reproductive effects based upon animal studies.
Medical conditions aggravated by exposure: Some people are said to be dangerously sensitive to minute amounts of sulfites in foods and some bronchodilator medicines preserved with sulfites.
Section 4: First aid measures
Eye and skin contact: Wash off contact area with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists.
Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Induce vomiting as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician immediately.
Section 5: Fire fighting measures
Flash point: NA
Autoignition point: NA
Flammability limits: upper: NA
Lower: NA
Extinguishing media: water, CO2, dry chemical or foam.
Section 6: Accidental release measures
Take up with absorbent materials. Place in small containers for disposal. Wash spill site after material pick up is complete.
Section 7: Handling and storage
Wear eye protection and gloves when working with this product.
This product absorbs oxygen from the air. Avoid direct solution contact with air as much as possible.
Avoid contact with eyes and skin. Do not ingest.
Store at room temperature. Keep away from heat and keep container closed.
Section 8: Exposure controls/ personal protection
Osha threshold limit: None listed.
Acgih threshold limit: 5 mg/m3 (TWA) as NaHSO3; 0.02 mg/m3 (TWA) as Co.
Protective equipment: Safety glasses, lab coat and gloves.
Section 9: Physical and chemical properties
State: Clear colorless liquid
Odor threshold: Odorless
Sensitivity to mechanical impact: None
Sensitivity to static discharge: None
Coefficient of oil/water distribution: None
Solubility in water: Soluble
pH: 9.7
Specific gravity: 1.06
Boiling point: Not determined
Melting point: Not determined
Vapor density: Not determined
Section 10: Stability and reactivity
Sulfite reacts with oxygen to form sulfate. Hazardous polymerization will not occur.
Incompatibles: Strong oxidizers, acids, high temperatures.
Hazardous decomposition product: May emit oxides of sulfur, cobalt and chloride when heated to decomposition.
Section 11: Toxicological information
Route of Exposure: Eyes, skin, respiratory tract
Teratogen Status: None
Mutagen Status: Effects have occurred in experimental animals with Co compound
Reproductive Toxicity: Adverse effects have occurred in experimental animals with Co compound
Carcinogen Status: 'Cobalt, inorganic compounds' are listed as a group 2B carcinogen by IARC
Section 12: Ecological information
Cobalt is toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment.
Section 13: Disposal considerations
Dispose of in a manner consistent with Federal, State and Local Regulations.
Section 14: Transport information
Product is not hazardous for transport.
Section 15: Regulatory information
EUROPEAN INFORMATION
Risk phrases: R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety phrases: S23 Do not breathe vapor. S24/25 Avoid contact with skin and eyes. S37/39 Wear suitable gloves and eye/face protection.
US/ CANADA INFORMATION
SARA/Title III: CoCl2 is listed under CERCLA.
Cal. Proposition 65: Ingredients not listed.
US TSCA Inventory: Ingredients are listed.
CPR Class: None.
TDG Class: None.
MSDS discloses elements required by the CPR.
Section 16: Other information
The above information is believed to be accurate and represents the best information currently available to us. All products are offered in accordance with the manufacturer\'s current production specifications and are intended solely for use in analytical testing. The manufacturer shall in noevent be liable for any injury, loss or damage resulting from the handling, use or misuse of these products.
Material safety data sheet
UN Number: None Allocated
Dangerous Goods Class: None Allocated
Other Names: Nil
Subsidiary Risk: None Allocated
Hazchem Code: None Allocated
Poisons Schedule: Not Scheduled
Uses: Analytical reagent for calibrating ORP / Redox sensors
#US/Canada/International:
24 Hour Emergency Information Telephone Numbers
CHEMTREC (USA): 800.424.9300
CANUTEC (Canada): 613.424.6666
International 703-527-3887
#Spain:
Centro Nacional de Toxicología
Teléfono: 91 5620420
Physical Description / Properties
Appearance: Yellow odorless liquid
Boiling Point (ºC): 100 (approx)
Vapor Pressure (mm of Hg @ 25ºC): 25 (approx)
Specific Gravity: 1
Flash Point (ºC): Not flammable
Flammability Limits (%): Not flammable
Solubility in Water (g/L): Completely miscible
Ingredients:
Chemical Entity
CAS NO.
Proportion
Potassium Chloride
7447-40-7
0.75% w/v
Potassium Ferricyanide
13746-66-2
0.11% w/v
Potassium Ferrocyanide
14459-95-1
0.14% w/v
Water
7732-18-5
to 100%
Health hazard information
Health Effects:
Swallowed: May be harmful if swallowed. May cause irritation of the gastric system.
Eye: May be irritating to eye tissue.
Skin: May irritate skin tissue.
Inhaled: Not considered a hazard with normal laboratory use. Mists may cause irritation of mucous membranes.
Chronic Effects: No data available
First Aid:
Swallowed: If conscious wash out mouth with water. Seek medical advice. Show this MSDS to medical practitioner.
Eye: Immediately hold eyelids open and flood with water for at least 15 minutes. Obtain medical aid. Show this MSDS to medical practitioner.
Skin: Remove contaminated clothing. Immediately wash skin thoroughly with water and mild soap. Seek medical advice if irritation persists. Show this MSDS to medical practitioner.
Inhaled: Remove from contaminated air. Maintain breathing with artificial respiration if necessary. Seek medical assistance. Show this MSDS to a doctor.
Advice to Doctor:
Treat symptomatically
Precautions for use
Exposure Limits: Work safe - None Established
Engineering Controls: Not usually required with normal use. If mists or aerosols generated, maintain personal exposure to minimal concentrations with extraction ventilation.
Personal Protection: Wear protective clothing including safety glasses and rubber or PVC gloves.
Flammability: Not flammable
Safe handling information
Storage & Transport: Store sealed in original container in a cool well ventilated situation away from foods and other chemicals. Observe good hygiene and housekeeping practices. No special transport requirements apply.
Spills & Disposal: Absorb spills with sand or vermiculite. Transfer carefully to disposal container. Dispose of in accordance with local regulations.
Fire/Explosion Hazard: Fire fighters should wear self contained breathing apparatus and impervious clothing if exposure to fumes is likely. Use water spray, foam or dry chemical to control fire situation if compatible with other chemical products in the vicinity.
Section 1: Product and company identification
Product name: Conductivity Solution
Product use: Standard
NFPA ratings: Health: 0 Flammability: 0 Reactivity: 0
#US/Canada/International:
24 Hour Emergency Information Telephone Numbers
CHEMTREC (USA): 800.424.9300
CANUTEC (Canada): 613.424.6666
International 703-527-3887
#Spain:
Centro Nacional de Toxicología
Teléfono: 91 5620420
Section 2: Composition/ information on ingredients
COMPONENT
CAS NO.
%
LD50 mg/kg
Sodium Chloride (NaCl)
7647-14-5
< 1
2,600 (ORL-RAT)
Deionized Water (H2O)
7732-18-5
> 99
190,000 (IPR-MUS)
Section 3: Hazards identification
Low hazard for normal use
Target organs: Eyes, skin
Acute toxicity: May cause irritation to eyes and skin
Chronic toxicity: No information found
Medical conditions aggravated by exposure: May cause stinging or irritation in an open cut
Section 4: First aid measures
Eye and skin contact: Wash off with large amounts of water
Ingestion: Drink large amounts of water. Consult physician.
Inhalation: Not hazardous.
Section 5: Fire fighting measures
Flash point: NA
Autoignition point: NA
Flammability limits: UPPER: NA
Lower: NA
Extinguishing media: Water, dry chemical, foam or CO
Section 6: Accidental release measures
Take up with absorbent material. Place in small container for disposal. Wash spill site with water after material pick up is complete.
Section 7: Handling and storage
Wear eye protection and gloves when working with this product.
Avoid contact with eyes and skin.
Store at room temperature. Keep away from heat and keep container closed.
Section 8: Exposure controls/ personal protection
OSHA & ACGIH threshold limit: None listed
Protective equipment: Safety glasses, lab coat and gloves
Section 9: Physical and chemical properties
State: clear colorless liquid
Odor threshold: none
Sensitivity to mechanical impact: none
Sensitivity to static discharge: none
Coefficient of oil/water distribution: none
Solubility in water: soluble
pH: approx. 7
Specific gravity: 1.0
Boiling point: approx. 100ºC
Melting point: not determined
Vapor density: not determined
Section 10: Stability and reactivity
Product is stable. Hazardous polymerization will not occur.
Incompatibles: Bromine trifluoride, potassium permanganate plus sulfuric acid.
Hazardous decomposition product: None
Section 11: Toxicological information
Route of Exposure: Eyes, skin.
Teratogen Status: None
Mutagen Status: None
Reproductive Toxicity: None
Carcinogen Status: None
Section 12: Ecological information
None available.
Section 13: Disposal considerations
Dispose of in a manner consistent with Federal, State and Local regulations.
Section 14: Transport information
Product is not hazardous for transport.
Section 15: Regulatory information
EUROPEAN INFORMATION:
Risk phrases: None
Safety phrases: S24/25 Avoid contact with skin and eyes.
US/ CANADA INFORMATION
SARA/Title III: Ingredients not listed
Cal. Proposition 65: Ingredients not listed
US TSCA Inventory: Ingredients are listed
CPR Class: None
TDG Class: None
MSDS discloses elements required by the CPR.
Section 16: Other information
The above information is believed to be accurate and represents the best information currently available to us. All products are offered in accordance with the manufacturer\'s current production specifications and are intended solely for use in analytical testing. The manufacturer shall in no event be liable for any injury, loss or damage resulting from the handling, use or misuse of these products.
Section 1: Product and company identification
Product name: Dissolved Oxygen Electrolyte Solution
Product use: Equipment maintenance
NFPA ratings: Health: 0 Flammability: 0 Reactivity: 0
#US/Canada/International:
24 Hour Emergency Information Telephone Numbers
CHEMTREC (USA): 800.424.9300
CANUTEC (Canada): 613.424.6666
International 703-527-3887
#Spain:
Centro Nacional de Toxicología
Teléfono: 91 5620420
Section 2: Composition/ information on ingredients
COMPONENT
CAS NO.
%
LD50 mg/kg
Water
7732-18-5
70
90000(ORL-RAT)
Sodium Tetraborat
1303-96-4
15
Sodium Chloride
7647-14-5
15
Section 3: Hazards identification
Classification of the chemical in accordance with paragraph (d) of §1910.1200
Not a dangerous substance according to GHS classification criteria. No known OSHA hazards.
GHS Classification
Section 4: First aid measures
Eye and skin contact: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water.
Ingestion: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Inhalation: In case of accident by inhalation: remove casualty to fresh air and keep at rest.
Section 5: Fire fighting measures
Flash point: NA
Autoignition point: NA
Flammability limits: UPPER: NA
Lower: NA
Extinguishing media: Use media suitable to extinguish surrounding fire.
Section 6: Accidental release measures
No health affects expected from the clean-up of this material if contact can be avoided. Follow personal protective equipment recommendations found in Section 8 of this (M)SDS Avoid breathing material. Avoid contact with skin and eyes. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation.
Section 7: Handling and storage
Avoid contact with skin and eyes.
Keep container tightly closed in a cool, well-ventilated place.
Green - general chemical storage.
Section 8: Exposure controls/ personal protection
OSHA & ACGIH threshold limit: None listed.
Engineering Measures: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to avoid overexposure.
Equipment (PPE): Lab coat, apron, eye wash, safety shower.
Respiratory Protection: No respiratory protection required under normal conditions of use. Respirator Type(s). None required where adequate ventilation is provided. If airborne concentrations are above the applicable exposure limits, use NIOSH/MSHA approved respiratory protection. Eye Protection Wear chemical splash goggles when handling this product. Have an eye wash station available.
Skin Protection: Avoid skin contact by wearing chemically resistant gloves, an apron and other protective equipment depending upon conditions of use. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work.
Gloves: No information available.
Section 9: Physical and chemical properties
Formula: See Section 3
Molecular Weight: No data available
Appearance: Colorless Depends upon product selection. The color additives do not affect product hazards. Liquid.
Odor: None
Odor: Threshold No data available
Dissolved Oxygen: Electrolyte Solution
Melting Point: Estimated 0 ºC
Boiling Point: 100 ºC
Flash Point: No data available
Flammable Limits in Air: No data available
Vapor Pressure: No data available
Evaporation Rate (BuAc=1): No data available
Vapor Density (Air=1): No data available
Specific Gravity: Approx. 1
Solubility in Water: Soluble
Log Pow (calculated): No data available
Autoignition Temperature: No data available
Decomposition Temperature: No data available
Viscosity: No data available
Percent Volatile by Volume: No data available
Section 10: Stability and reactivity
Reactivity: Not generally reactive under normal conditions.
Chemical Stability: Stable under normal conditions.
Conditions to Avoid: None known.
Incompatible Materials: Water-reactive materials
Hazardous Decomposition -- Products: Sodium Oxides, Potassium Oxide, Phosphorus compounds
Hazardous Polymerization: Will not occur
Section 11: Toxicological information
Route of Entry: Ingestion, skin and eye contact.
Teratogen Status: None.
Mutagen Status: No evidence of a mutagenic effect.
Sensitization: No evidence of a sensitization effect.
Reproductive Toxicity: No evidence of negative reproductive effects.
Target Organ Effects:
Acute: Respiratory system, Cardiovascular system, Musculoskeletal system.
Chronic: No information available.
Section 12: Ecological information
Overview: This material is not expected to be harmful to the ecology.
Mobility: This material is expected to have high mobility in soil. It absorbs weakly to most soil types.
Persistence: Dissolved into water.
Bioaccumulation: Bioconcentration is not expected to occur.
Degradability: No data.
Other Adverse Effects: No data.
Section 13: Disposal considerations
Dispose of in a manner consistent with Federal, State and Local regulations. Always contact a permitted waste disposer (TSD) to assure compliance.
Section 14: Transport information
Product is not hazardous for transport.
Section 15: Regulatory information
EUROPEAN INFORMATION:
Risk phrases: None.
Safety phrases: S24/25 Avoid contact with skin and eyes.
US/ CANADA INFORMATION
SARA/Title III: Ingredients not listed
Cal. Proposition 65: Ingredients not listed
US TSCA Inventory: Ingredients are listed
CPR Class: None
TDG Class: None
MSDS discloses elements required by the CPR.
Section 16: Other information
The above information is believed to be accurate and represents the best information currently available to us. All products are offered in accordance with the manufacturer\'s current production specifications and are intended solely for use in analytical testing. The manufacturer shall in no event be liable for any injury, loss or damage resulting from the handling, use or misuse of these products.
Section 1: Product and company identification
Product name: Solution of formazine 4000 NTU Product use: Equipment maintenance
Article number: 1SF007, 1SF008, 1SF009 Relevant identified uses of the substance or mixture and uses advised against: No further relevant information available. Application of the substance / the mixture Reagent for analysis.
Details of the supplier of the safety data sheet Manufacturer/Supplier: Orchidis laboratoire, 90 rue du Pr Milliez 94506. Champigny/Marne, France +33 1 55 09 10 10 mel: safety@orchidis.com
Further information obtainable from: - - - Emergency telephone number: Urgences n°unique d\'appel européen: 112 (UE) Urgences: centre anti poison +33(0)1 40 05 48 48 Liste des centres anti poison: ORFILA +33(0)1 45 42 59 59
#US/Canada/International:
24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887
#Spain:
Section 2: Composition/ information on ingredients
COMPONENT
CAS NO.
%
Other
Methenamine
100-97-0
2.5 – 5%
EINECS: 202-905-8
Flam. Liq. 1, H224; Flam. Sol. 2, H228;
Skin Sens. 1, H317
hydrazinium(2+) sulphate
10034-93-2
0.1 – 1%
EINECS: 233-110-4
Acute Tox. 3, H311; Acute Tox. 2, H330;
Carc. 1A, H350;
Acute Tox. 4, H302;
Skin Sens. 1, H317
Section 3: Hazards identification
Classification of the substance or mixture: Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Carc. 1A - H350 May cause cancer. GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
Labeling according to Regulation (EC) No 1272/2008 The product is classified and labeled according to the CLP regulation. Hazard pictograms GHS07 GHS08
Signal word Danger
Hazard-determining components of labelling: methenamine hydrazinium(2+) sulphate
Hazard statements
H317 May cause an allergic skin reaction. H350 May cause cancer.
Precautionary statements
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P321 - Specific treatment (see on this label). P308+P313 - IF exposed or concerned: Get medical advice/attention. P405 - Store locked up. P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.
Additional information: Restricted to professional users.
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable. vPvB: Not applicable.
Section 4: First aid measures
Description of first aid measures
General information: Immediately remove any clothing soiled by the product.
After inhalation:
Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: If symptoms persist consult doctor.
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Section 5: Fire fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture No further relevant information available.
Advice for firefighters
Protective equipment: No special measures required.
Section 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures Not required.
Environmental precautions: Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment.
Section 7: Handling and storage
Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about fire - and explosion protection: Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep container tightly sealed. Specific end use(s) No further relevant information available.
Section 8: Exposure controls/ personal protection
Additional information about design of technical facilities: No further data; see item 7.
Control parameters
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information: The lists valid during the making were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Store protective clothing separately.
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection:
Tightly sealed goggles
Section 9: Physical and chemical properties
Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour:Whitish Odour: Odourless Odour threshold: Not determined. pH-value at 20 °C: 6 Change in condition Melting point/Melting range: Undetermined Boiling point/Boiling range: 100 °C Flash point: Not applicable. Flammability (solid, gaseous): Not applicable. Ignition temperature: Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Not determined. Upper: Not determined. Vapour pressure: Not determined. Density at 20 °C: 1 g/cm3 Relative density: Not determined. Vapour density: Not determined. Evaporation rate: Not determined. Solubility in / Miscibility with water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water): Not determined. Viscosity: Not determined. Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 0.0 % Water: 94.5 % Solids content: 5.0 % Other information: No further relevant information available.
Section 10: Stability and reactivity
Reactivity No further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No further relevant information available.
Incompatible materials: No further relevant information available.
Hazardous decomposition products: No dangerous decomposition products known.
Section 11: Toxicological information
11.1 Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. LD/LC50 values relevant for classification: 10034-93-2 hydrazinium(2+) sulphate Oral LD50 601 mg/kg (rat) Primary irritant effect: Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/irritation Based on available data, the classification criteria are not met. Respiratory or skin sensitisation May cause an allergic skin reaction. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity May cause cancer. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met.
Section 12: Ecological information
Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.
Section 13: Disposal considerations
Waste treatment methods
Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
Section 14: Transport information
UN-Number
ADR, ADN, IMDG, IATA - Void
UN proper shipping name
ADR, ADN, IMDG, IATA - Void
Transport hazard class(es)
ADR, ADN, IMDG, IATA
Class - void
Packing group
ADR, IMDG, IATA - Void
Environmental hazards:
Marine pollutant: No
Special precautions for user - Not applicable.
Transport in bulk according to Annex II of Marpol and the IBC Code - Not applicable.
UN \"Model Regulation\": Void
Additional Information:
This product may be shipped as part of a chemical kit composed of various compatible dangerous goods for analytical or testing purposes. This kit would have the following classification : proper shipping name: chemical kit, hazard class 9, UN number 3316, package group II, EMS code : F-A, S-P
Section 15: Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Labeling according to Regulation (EC) No 1272/2008
The product is classified and labeled according to the CLP regulation.
Hazard pictograms
GHS07 GHS08
Signal word Danger
Hazard-determining components of labeling:
methenamine hydrazinium(2+) sulphate
Hazard statements
H317 May cause an allergic skin reaction. H350 May cause cancer.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P321 Specific treatment (see on this label). P308+P313 IF exposed or concerned: Get medical advice/attention. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed.
REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
National regulations:
Additional classification according to Decree on Hazardous Materials, Annex II:
Carcinogenic hazardous material group III (dangerous).
Information about limitation of use:
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
Section 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
Relevant phrases:
H224 Extremely flammable liquid and vapour. H228 Flammable solid. H302 Harmful if swallowed. H311 Toxic in contact with skin. H317 May cause an allergic skin reaction. H330 Fatal if inhaled. H350 May cause cancer.
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Flam. Liq. 1: Flammable liquids -- Category 1 Flam. Sol. 2: Flammable solids -- Category 2 Acute Tox. 4: Acute toxicity -- Category 4 Acute Tox. 3: Acute toxicity -- Category 3 Acute Tox. 2: Acute toxicity -- Category 2 Skin Sens. 1: Skin sensitisation -- Category 1 Carc. 1A: Carcinogenicity -- Category 1A Carc. 1A: Carcinogenicity -- Category 1A
Section 1: Identification of the substance/mixture and of the company/undertaking
#US/Canada/International:
24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800.424.9300 CANUTEC (Canada): 613.424.6666 International 703-527-3887
#Spain:
Section 2: Hazards identification
2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 The product is not classified, according to the CLP regulation. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 Void Hazard pictograms Void Signal word Void Hazard statements Void Additional information: Safety data sheet available on request. 2.3 Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.
Section 3: Composition/information on ingredients
3.2 Chemical characterisation: Mixtures Description: Mixture of substances listed below with nonhazardous additions.
Dangerous components:
CAS: 56-81-5EINECS: 200-289-5
glycerol
substance with a Community workplace exposure limit
25-50%
CAS: 10043-35-3EINECS: 233-139-2
boric acid
Repr. 1B, H360FD
0.1-1%
SVHC
10043-35-3
boric acid
Additional information: For the wording of the listed hazard phrases refer to section 16.
Section 4: First aid measures
4.1 Description of first aid measures General information: No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.
Section 5: Firefighting measures
5.1 Extinguishing media Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. 5.2 Special hazards arising from the substance or mixture No further relevant information available. 5.3 Advice for firefighters Protective equipment: No special measures required.
Section 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures Not required. 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). 6.4 Reference to other sections No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
Section 7: Handling and storage
7.1 Precautions for safe handling No special measures required. Information about fire - and explosion protection: No special measures required. 7.2 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. 7.3 Specific end use(s) No further relevant information available.
Section 8: Exposure controls/personal protection
Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters Ingredients with limit values that require monitoring at the workplace: 56-81-5 glycerol WEL: Long-term value: 10 mg/m³ Additional information: The lists valid during the making were used as basis. 8.2 Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Respiratory protection: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling
Section 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: Pink Odour: Odourless Odour threshold: Not determined. pH-value at 20 °C: 1 Change in condition Melting point/freezing point: Undetermined. Initial boiling point and boiling range: 100 °C Flash point: 160 °C Flammability (solid, gas): Not applicable. Ignition temperature: 400 °C Decomposition temperature: Not determined. Auto-ignition temperature: Product is not selfigniting. Explosive properties: Product does not present an explosion hazard. Explosion limits: Lower: 0.9 Vol % Upper: Not determined. Vapour pressure: Not determined. Density at 20 °C: 1.174 g/cm³ Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Not miscible or difficult to mix. Partition coefficient: n-octanol/water: Not determined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 26.9 % Water: 51.0 % Solids content: 0.0 % 9.2 Other information No further relevant information available.
Section 10: Stability and reactivity
10.1 Reactivity No further relevant information available. 10.2 Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions No dangerous reactions known. 10.4 Conditions to avoid No further relevant information available. 10.5 Incompatible materials: No further relevant information available. 10.6 Hazardous decomposition products: No dangerous decomposition products known.
Section 11: Toxicological information
11.1 Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. LD/LC50 values relevant for classification: 56-81-5 glycerol Oral LD50 12,600 mg/kg (rat) 7447-40-7 potassium chloride Oral LD50 2,600 mg/kg (rat) 7778-77-0 potassium dihydrogenorthophosphate Oral LD50 4,640 mg/kg (rat) 10043-35-3 boric acid Oral LD50 2,660 mg/kg (rat) Primary irritant effect: Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/irritation Based on available data, the classification criteria are not met. Respiratory or skin sensitisation Based on available data, the classification criteria are not met. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met.
Section 12: Ecological information
12.1 Toxicity Aquatic toxicity: No further relevant information available. 12.2 Persistence and degradability No further relevant information available. 12.3 Bioaccumulative potential No further relevant information available. 12.4 Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. 12.5 Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. 12.6 Other adverse effects No further relevant information available.
Section 13: Disposal considerations
13.1 Waste treatment methods Recommendation Smaller quantities can be disposed of with household waste. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations.
Section 14: Transport information
14.1 UN-Number ADR, ADN, IMDG, IATA Void 14.2 UN proper shipping name ADR, ADN, IMDG, IATA Void 14.3 Transport hazard class(es) ADR, ADN, IMDG, IATA Class Void 14.4 Packing group ADR, IMDG, IATA Void 14.5 Environmental hazards: Marine pollutant: No 14.6 Special precautions for user Not applicable. 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. UN \"Model Regulation\": Void Additional Informations This product may be shipped as part of a chemical kit composed of various compatible dangerous goods for analytical or testing purposes. This kit would have the following classification : proper shipping name : chemical kit, hazard class 9, UN number 3316, package group II, EMS code : F-A, S-P
Section 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Labelling according to Regulation (EC) No 1272/2008 Void Hazard pictograms Void Signal word Void Hazard statements Void Directive 2012/18/EU Named dangerous substances - ANNEX I None of the ingredients is listed. National regulations: Other regulations, limitations and prohibitive regulations Substances of very high concern (SVHC) according to REACH, Article 57 10043-35-3 boric acid 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
Section 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H360FD May damage fertility. May damage the unborn child. Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic SVHC: Substances of Very High Concern vPvB: very Persistent and very Bioaccumulative Repr. 1B: Reproductive toxicity -- Category 1B
Centro Nacional de Toxicología Teléfono: 91 562042
1.1 Product identifier Trade name: Solution de Conservation Article number: 1SC009, 1SC021, 1SC035 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Reagent for analysis. 1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: Aqualabo 90 rue du Professeur P.Milliez - 94506 Champigny-sur-Marne - France +33 1 55 09 10 10 mail: www.aqualabo.fr (all of our SDS can be downloaded from our website, section \"Services\"). Further information obtainable from: - - - 1.4 Emergency telephone number: Urgences n°unique d\'appel européen : 112 (UE) Urgences : Centre anti poison +33(0)1 40 05 48 48 Liste des centres anti poison : ORFILA +33(0)1 45 42 59 59
Centro Nacional de Toxicología Teléfono: 91 5620420